Crystal structure and hydrogen graph motifs in anilinium hydrogensulfate

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Anilinium hydrogen sulfate

The asymmetric unit of the title compound, C(6)H(8)N(+)·HSO(4) (-), contains two cations and two anions which are linked to each other through N-H⋯O hydrogen bonds, formed by all H atoms covalently bonded to the N atoms. In addition, strong O-H⋯O anion-anion hydrogen-bond inter-actions are also observed.

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Periodic-Graph Approaches in Crystal Structure Prediction

The explosive growth in inorganic and organic materials chemistry has seen a great upsurge in the synthesis of crystalline materials with extended framework structures (zeolites, coordination polymers/coordination networks, metal–organic frameworks (MOFs), supramolecular architectures formed by hydrogen bonds and/or halogen bonds, etc.). There is a concomitant interest in simulating such materi...

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The crystal structure of the title salt, C8H12N(+)·C4H3O4 (-), consists of a 2,5-di-methyl-anilinium cation and an hydrogen maleate anion. In the anion, a strong intra-molecular O-H⋯O hydrogen bond is observed, leading to an S(7) graph-set motif. In the crystal, the cations and anions pack in alternating layers parallel to (001). The ammonium group undergoes inter-molecular N-H⋯O hydrogen-bondi...

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Crystal structure of 3,4-di­chloro­anilinium hydrogen phthalate

In the title salt, C6H6Cl2N(+)·C8H5O4 (-), the carb-oxy-lic acid and carboxyl-ate groups of the anion form dihedral angles of 20.79 (19) and 74.76 (14)°, respectively, with the plane of the benzene ring. In the crystal, mol-ecules are assembled into a two-dimensional polymeric network parallel to (100) via N-H⋯O and O-H⋯O hydrogen bonds. In addition, within the layer, there are π-π stacking int...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography

سال: 2011

ISSN: 0108-7673

DOI: 10.1107/s0108767311085564